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Pericyclic Rearrangements

by Andrew

Claisen

A [3,3]-sigmatropic rearrangement (see Pericyclics). The driving force for the reaction is formation of the strong C=O bond

Cope – similar to Claisen

Also a [3,3]-sigmatropic rearrangement. The driving force in this case is opening of the strained four membered ring.
Rearrangements to Electron-Deficient Nitrogen
Introduction and Oxidations on the Alcohol Level

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